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Shift | A Wisdom Archive on Shift |  | Shift A selection of articles related to Shift |  |
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shift, Shift, Shapeshift
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| ARTICLES RELATED TO Shift | |  |  |  | Shift: Encyclopedia II - Chemical shift - Chemical shift referencingChemical shift is usually expressed in parts per million (ppm) by frequency, because it is calculated from:
Since the numerator is usually in hertz, and the denominator in megahertz, delta is expressed in ppm.
The detected frequencies (in Hz) for 1H, 13C, and 29Si nuclei are usually referenced against TMS (tetramethylsilane), which is assigned the chemical shift of zero. Other standard materi ...
See also:Chemical shift, Chemical shift - Introduction, Chemical shift - Chemical shift referencing, Chemical shift - 1H chemical shift, Chemical shift - Detailed table of 1H chemical shifts in CH CH2 and CH3 next to functional group α-position in aliphatic compounds [ppm], Chemical shift - 13C chemical shift, Chemical shift - DEPT spectra, Chemical shift - Magnetic properties of most common nuclei, Chemical shift - The fastest way to understanding spectra Read more here: » Chemical shift: Encyclopedia II - Chemical shift - Chemical shift referencing |
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| | |  |  |  | Shift: Encyclopedia II - Chemical shift - IntroductionAn atomic nucleus can have a magnetic moment (nuclear spin), which gives rise to different energy levels and (resonance frequencies) in a magnetic field. The total magnetic field experienced by a nucleus includes local magnetic fields induced by currents of electrons in the molecular orbitals (note that electrons have a magnetic moment themselves). The electron distribution of the same type of nucleus (e.g. 1H, 13C, 15N) usually varies according to the local geometry (binding partners, bond lengths, angles be ...
See also:Chemical shift, Chemical shift - Introduction, Chemical shift - Chemical shift referencing, Chemical shift - 1H chemical shift, Chemical shift - Detailed table of 1H chemical shifts in CH CH2 and CH3 next to functional group α-position in aliphatic compounds [ppm], Chemical shift - 13C chemical shift, Chemical shift - DEPT spectra, Chemical shift - Magnetic properties of most common nuclei, Chemical shift - The fastest way to understanding spectra Read more here: » Chemical shift: Encyclopedia II - Chemical shift - Introduction |
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| | |  |  |  | Shift: Encyclopedia II - Shifting cultivation - Shifting cultivation in the contemporary world and global environmental changeThe estimated rate of deforestation in Southeast Asia in 1990 was 34,000 km² per year (FAO 1990, quoted in Potter 1993). In Indonesia alone it was estimated 13,100 km² per year were being lost, 3,680 km² per year from Sumatra and 3,770 km² from Kalimantan, of which 1,440 km² were due to the fires of 1982 to 1983. Since those estimates were made huge fires have ravaged Indonesian forests during the 1997 to 1998 El Niño associated drought.
“Shifting cultivation” was assessed by the FAO to be one of the causes of this deforesta ...
See also:Shifting cultivation, Shifting cultivation - Similar terms, Shifting cultivation - Subsistence, Shifting cultivation - The political ecology of shifting cultivation, Shifting cultivation - Stereotypes: primitive backward wasteful unproductive, Shifting cultivation - Shifting cultivation in Europe, Shifting cultivation - Simple societies shifting cultivation and environmental change, Shifting cultivation - Shifting cultivation in the contemporary world and global environmental change, Shifting cultivation - Conclusion Read more here: » Shifting cultivation: Encyclopedia II - Shifting cultivation - Shifting cultivation in the contemporary world and global environmental change |
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|  |  |  | Shift: Encyclopedia II - Shifting cultivation - Simple societies shifting cultivation and environmental changeThe forests of Europe were destroyed by the seemingly inexorable ‘advances’ of civilisation, industrialisation and warfare, the sort of ‘advances’ that many of those who criticised shifting cultivators in the 19th century thought were desirable and indicative of “higher cultures”. The same sort of processes are leading to the destruction of tropical forests in the last decade of the 20th century. So ‘advances’ in civilization, now known as ‘development’, have not resolved these problems. The problems are located not in th ...
See also:Shifting cultivation, Shifting cultivation - Similar terms, Shifting cultivation - Subsistence, Shifting cultivation - The political ecology of shifting cultivation, Shifting cultivation - Stereotypes: primitive backward wasteful unproductive, Shifting cultivation - Shifting cultivation in Europe, Shifting cultivation - Simple societies shifting cultivation and environmental change, Shifting cultivation - Shifting cultivation in the contemporary world and global environmental change, Shifting cultivation - Conclusion Read more here: » Shifting cultivation: Encyclopedia II - Shifting cultivation - Simple societies shifting cultivation and environmental change |
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|  |  |  | Shift: Encyclopedia II - Phase-shift keying - IntroductionThere are three major classes of digital modulation techniques used for transmission of digitally represented data:
Amplitude-shift keying (ASK)
Frequency-shift keying (FSK)
Phase-shift keying (PSK)
All convey data by changing some aspect of a base signal, the carrier wave, (usually a sinusoid) in response to a data signal. In the case of PSK, the phase is changed to represent the data signal. There are two fundamental ways of utilizing the phase of a signal in this way:
By viewing th ...
See also:Phase-shift keying, Phase-shift keying - Introduction, Phase-shift keying - Ideal structure, Phase-shift keying - Transmitter, Phase-shift keying - Receiver, Phase-shift keying - Definitions, Phase-shift keying - Applications, Phase-shift keying - Binary Phase-shift Keying BPSK, Phase-shift keying - Implementation, Phase-shift keying - Quadrature Phase-shift Keying QPSK, Phase-shift keying - Implementation, Phase-shift keying - QPSK signal in the time domain, Phase-shift keying - Offset QPSK OQPSK, Phase-shift keying - π / 4–QPSK, Phase-shift keying - Higher-order PSK, Phase-shift keying - Differential Encoding, Phase-shift keying - Example: Differentially encoded BPSK, Phase-shift keying - Differential Phase-shift Keying DPSK, Phase-shift keying - Notes Read more here: » Phase-shift keying: Encyclopedia II - Phase-shift keying - Introduction |
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|  |  |  | Shift: Encyclopedia II - Phase-shift keying - Differential Phase-shift Keying DPSKFor a signal that has been differentially encoded, there is an obvious alternative method of demodulation. Instead of demodulating as usual and ignoring carrier-phase ambiguity, the phase between two successive received symbols is compared and used to determine what the data must have been. When differential encoding is used in this manner, the scheme is known as differential phase-shift keying (DPSK). Note that this is subtly different to just differentially-encoded PSK since, upon reception, the received symbols are not decoded one-by-on ...
See also:Phase-shift keying, Phase-shift keying - Introduction, Phase-shift keying - Ideal structure, Phase-shift keying - Transmitter, Phase-shift keying - Receiver, Phase-shift keying - Definitions, Phase-shift keying - Applications, Phase-shift keying - Binary Phase-shift Keying BPSK, Phase-shift keying - Implementation, Phase-shift keying - Quadrature Phase-shift Keying QPSK, Phase-shift keying - Implementation, Phase-shift keying - QPSK signal in the time domain, Phase-shift keying - Offset QPSK OQPSK, Phase-shift keying - π / 4–QPSK, Phase-shift keying - Higher-order PSK, Phase-shift keying - Differential Encoding, Phase-shift keying - Example: Differentially encoded BPSK, Phase-shift keying - Differential Phase-shift Keying DPSK, Phase-shift keying - Notes Read more here: » Phase-shift keying: Encyclopedia II - Phase-shift keying - Differential Phase-shift Keying DPSK |
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|  |  |  | Shift: Encyclopedia II - Phase-shift keying - Binary Phase-shift Keying BPSKBPSK is the simplest form of PSK. It uses two phases which are separated by 180° and so can also be termed 2-PSK. It does not particularly matter exactly where the constellation points are positioned, and in this figure they are shown on the real axis, at 0° and 180°. This modulation is the most robust of all the PSKs since it takes serious distortion to make the demodulator reach an incorrect decision. It is, however, only able to modulate at 1bit/symbol (as seen in the figure) and so is unsuitable for high data-rate applications.
The bit error ...
See also:Phase-shift keying, Phase-shift keying - Introduction, Phase-shift keying - Ideal structure, Phase-shift keying - Transmitter, Phase-shift keying - Receiver, Phase-shift keying - Definitions, Phase-shift keying - Applications, Phase-shift keying - Binary Phase-shift Keying BPSK, Phase-shift keying - Implementation, Phase-shift keying - Quadrature Phase-shift Keying QPSK, Phase-shift keying - Implementation, Phase-shift keying - QPSK signal in the time domain, Phase-shift keying - Offset QPSK OQPSK, Phase-shift keying - π / 4–QPSK, Phase-shift keying - Higher-order PSK, Phase-shift keying - Differential Encoding, Phase-shift keying - Example: Differentially encoded BPSK, Phase-shift keying - Differential Phase-shift Keying DPSK, Phase-shift keying - Notes Read more here: » Phase-shift keying: Encyclopedia II - Phase-shift keying - Binary Phase-shift Keying BPSK |
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|  |  |  | Shift: Encyclopedia II - Chemical shift - 1H chemical shift
Chemical shift - Detailed table of 1H chemical shifts in CH CH2 and CH3 next to functional group α-position in aliphatic compounds [ppm].
Chemical shift values are not precise, but typical - they are to be therefore regarded mainly as orientational. Deviations are in ±0.2 ppm range, sometimes more. The exact value of chemical shift depends on molecular structure and the solvent in which t ...
See also:Chemical shift, Chemical shift - Introduction, Chemical shift - Chemical shift referencing, Chemical shift - 1H chemical shift, Chemical shift - Detailed table of 1H chemical shifts in CH CH2 and CH3 next to functional group α-position in aliphatic compounds [ppm], Chemical shift - 13C chemical shift, Chemical shift - DEPT spectra, Chemical shift - Magnetic properties of most common nuclei, Chemical shift - The fastest way to understanding spectra Read more here: » Chemical shift: Encyclopedia II - Chemical shift - 1H chemical shift |
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|  |  |  | Shift: Encyclopedia II - Phase-shift keying - Quadrature Phase-shift Keying QPSKSometimes known as quaternary or quadriphase PSK or 4-PSK, QPSK uses four points on the constellation diagram, equispaced around a circle. With four phases, QPSK can encode two bits per symbol, shown in the diagram with Gray coding to minimize the BER — twice the rate of BPSK. Analysis shows that this may be used either to double the data rate compared to a BPSK system while maintaining the bandwidth of the si ...
See also:Phase-shift keying, Phase-shift keying - Introduction, Phase-shift keying - Ideal structure, Phase-shift keying - Transmitter, Phase-shift keying - Receiver, Phase-shift keying - Definitions, Phase-shift keying - Applications, Phase-shift keying - Binary Phase-shift Keying BPSK, Phase-shift keying - Implementation, Phase-shift keying - Quadrature Phase-shift Keying QPSK, Phase-shift keying - Implementation, Phase-shift keying - QPSK signal in the time domain, Phase-shift keying - Offset QPSK OQPSK, Phase-shift keying - π / 4–QPSK, Phase-shift keying - Higher-order PSK, Phase-shift keying - Differential Encoding, Phase-shift keying - Example: Differentially encoded BPSK, Phase-shift keying - Differential Phase-shift Keying DPSK, Phase-shift keying - Notes Read more here: » Phase-shift keying: Encyclopedia II - Phase-shift keying - Quadrature Phase-shift Keying QPSK |
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|  |  |  | Shift: Encyclopedia II - Chemical shift - 13C chemical shiftChemical shifts of 13C atoms follow the same principles as those of 1H, with the difference of 1H having greater relative sensitivity (that is, it is more easily detected). In addition to former fact, in 13C-NMR the intensity of the signal is not directionally proportional to the number of equivalent 13C atoms (unlike in 1H), but is a function of instrumental parameters, length, and delay of the pulse. Chemical shifts of 13C are bigger (more ppm). There are a number ...
See also:Chemical shift, Chemical shift - Introduction, Chemical shift - Chemical shift referencing, Chemical shift - 1H chemical shift, Chemical shift - Detailed table of 1H chemical shifts in CH CH2 and CH3 next to functional group α-position in aliphatic compounds [ppm], Chemical shift - 13C chemical shift, Chemical shift - DEPT spectra, Chemical shift - Magnetic properties of most common nuclei, Chemical shift - The fastest way to understanding spectra Read more here: » Chemical shift: Encyclopedia II - Chemical shift - 13C chemical shift |
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| | | | | |  |  |  | Shift: Encyclopedia II - Shifting cultivation - Stereotypes: primitive backward wasteful unproductiveDespite this, shifting cultivation remains negatively stereotyped. Shifting cultivation systems are perceived both by the supposedly well informed as well as the general public, as primitive, backward, wasteful, unproductive, exploitative and the cause of widespread environmental degradation. Shifting cultivators are blamed for the destruction of much of the world’s tropical forests, land degradation, atmospheric pollution and global climatic change.
While contemporary manifestations of these attitudes towards shifting cultivators a ...
See also:Shifting cultivation, Shifting cultivation - Similar terms, Shifting cultivation - Subsistence, Shifting cultivation - The political ecology of shifting cultivation, Shifting cultivation - Stereotypes: primitive backward wasteful unproductive, Shifting cultivation - Shifting cultivation in Europe, Shifting cultivation - Simple societies shifting cultivation and environmental change, Shifting cultivation - Shifting cultivation in the contemporary world and global environmental change, Shifting cultivation - Conclusion Read more here: » Shifting cultivation: Encyclopedia II - Shifting cultivation - Stereotypes: primitive backward wasteful unproductive |
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