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Ruthenium - Organometallic chemistry

Ruthenium - Organometallic chemistry: Encyclopedia II - Ruthenium - Organometallic chemistry

It is quite easy to form compounds with carbon ruthenium bonds, these compounds tend to be darker and react more quickly than the osmium compounds. Recently Prof Tony Hill and his co-workers have been making compounds of ruthenium in which a boron atom binds to the metal atom. The organometallic ruthenium compound that is easiest to make is RuHCl(CO)(PPh3)3. This compound has two forms (yellow and pink) that are identical onc ...

See also:

Ruthenium, Ruthenium - Notable characteristics, Ruthenium - Applications, Ruthenium - History, Ruthenium - Occurrence, Ruthenium - Compounds, Ruthenium - Isotopes, Ruthenium - Organometallic chemistry, Ruthenium - Precautions

Ruthenium, Ruthenium - Applications, Ruthenium - Compounds, Ruthenium - History, Ruthenium - Isotopes, Ruthenium - Notable characteristics, Ruthenium - Occurrence, Ruthenium - Organometallic chemistry, Ruthenium - Precautions

Ruthenium: Encyclopedia II - Ruthenium - Organometallic chemistry



Ruthenium - Organometallic chemistry

It is quite easy to form compounds with carbon ruthenium bonds, these compounds tend to be darker and react more quickly than the osmium compounds. Recently Prof Tony Hill and his co-workers have been making compounds of ruthenium in which a boron atom binds to the metal atom.

The organometallic ruthenium compound that is easiest to make is RuHCl(CO)(PPh3)3. This compound has two forms (yellow and pink) that are identical once they are dissolved but different in the solid state.

An organometallic compound similar to ruthenocene, bis(2,4-dimethylpentadienyl)ruthenium, is readily synthesized in near quantitative yields and has applications in vapor-phase deposition of metallic ruthenium, as well as in catalysis, including Fischer-Tropsch synthesis of transportation fuels.

Important catalysts based on ruthenium are Grubbs' Catalyst and Roper's complex.

Other related archives

1844, Cd, Fischer-Tropsch synthesis, Gottfried Osann, Grubbs' Catalyst, H, Hydrogen sulfide, Jedrzej Sniadecki, Jöns Berzelius, K, Karl Klaus, Latin, Organometallic, Pyroxenite, Roper's complex, S, South Africa, Sudbury, Ontario, Ural Mountains, alloy, alloys, ammonium, amu, aqua regia, arc welding, argon, atomic number, atomic weights, beta emission, bio-accumulates, carcinogenic, catalyst, catalysts, chemical element, compounds, decay mode, decay product, discovered, electrodeposition, electron capture, half-life, halogens, hydrogen, isotopes, jet engines, molybdenum, oil refineries, olefin metathesis, organometallic, osmium, osmium tetroxide, oxidation states, oxidize, palladium, pentlandite, periodic table, platinum, platinum group, radioisotopes, rhodium, solar energy, superalloys, superconductive, technetium, titanium, toxic, transition metal



Adapted from the Wikipedia article "Organometallic chemistry", under the G.N U Free Docmentation License. Please also see http://en.wikipedia.org/wiki

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